Copper(II) humate mobility in kaolinite soil     

J. Wu  L. J. West  D. I. Stewart   《Engineering Geology》2001,60(1-4):275-284

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.  相似文献   

Oxygen Isotope Exchange Kinetics Between Coexisting Minerals and Water in the Aral Granite Pluton of the Altay Mountains, Northern Xinjiang   总被引：2，自引：0，他引：2  

Liu Wei  Research Center of Mineral Resources Exploration  Chinese Academy of Sciences  Chinese Academy of Sciences  BeijingHe Baichu  Changsha Institute of Geotectonics  Chinese Academy of Sciences  Changsh  Hunanand Chen ZhenshengYichang Institute of Geology  Mineral Resources  Chinese Academy of GeologicalSciences  Yichang  Hubei 《《地质学报》英文版》1996,70(4)

Coexisting quartz, feldspar and biotite vary widely in their δ18O values and display a remarkable 18O/16O disequilibrium relation; especially, a quartz-feldspar reversal (△ 18OQUartz_feldspar< 0) exsists in the Aral granite pluton of the Altay Mountains, northern Xinjiang. The 18O / 16O exchange reaction definitely occurred between granite and water. Initial δ18O values of the granite and exotic fluid are evaluated by the mass balance consideration. The conventional method of discrimination between various magma derivations simply with δ18O values of either whole rock or separate minerals is misleading and unreliable. Experiments carried out by the authors show that the 18O / 16O exchange reaction is not accompanied by what geologists describe as petrological and mineralogical alteration effect. This decoupling relation implies that exchange reaction occurs at a relatively high temperature during subsolidus-postmagmatic cooling of magmas. The exchange mechanism is mainly diffusion-controlled. It is  相似文献   

Kinetics of redox cycling of iron coupled with fulvic acid     

Yiwei Deng  Werner Stumm 《Aquatic Sciences - Research Across Boundaries》1993,55(2):103-111

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.  相似文献   

Brønsted reactions on oxide mineral surfaces and the temperature-dependence of their dissolution rates     

William H. Casey  Marcus A. Cheney 《Aquatic Sciences - Research Across Boundaries》1993,55(4):304-313

The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ^–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.  相似文献   

低Peclet数下剪切流中气溶胶粒子的传质率     

温景嵩  曾庆存  王永光 《大气科学》1994,18(1):105-112

本文研究了低Péclet数下剪切流中气溶胶粒子的传质率。Péclet数(Pe)是物质浓度的对流输送项对分子扩散项的比。它等于Reynolds数(Re)与Schmidt数的(Sc)之积。本文应用奇异扰动方法得到了无因次传质率Nu(Nusselt数)在小Péclet数条件下的四项渐近展式，因而?改进了前人的结果。  相似文献   

旋转电极法研究盐类溶解─LiCl、NaCl、KCl在水中的溶解动力学     

陈若愚  夏树屏  高世扬 《盐湖研究》1994,(4)

利用旋转盘装置结合离子选择电极研究了ＬｉＣｌ、ＮａＣｌ、ＫＣｌ在２０℃～３５℃水中溶解动力学，得到了溶解动力学方程．  相似文献   

Behandlung von anilinhaltigem Abwasser mit Fentons Reagenz Treatment of Aniline Containing Waste Water by Fenton's Reagent     

B. Funke  M. Kolb  P. Jaser  R. Braun 《洁净——土壤、空气、水》1994,22(1):6-9

A chemical-physical method for treatment of aniline containing waste water was developed. At the chemical stage aniline is polymerized by Fenton's reagent. Thus insoluble polyaniline precipitates. The best reaction conditions are: pH-value of 2–3, stepwise dosing of 60 mL H₂O₂ (30%) and 12 mL saturated FeSO₄-solution per litre waste water. The molar ratio Fe(II): H₂O₂ amounts to 0.3:10. The concentration of aniline is reduced by this chemical treatment from about 20 g/L to 30–40 mg/L. By adsorption at activated charcoal the concentration of aniline can be reduced further to 0.2 mg/L. The resulting sludge can easily be dewatered in a chamber filter press.  相似文献   

铅在高岭石表面的解吸动力学   总被引：3，自引：0，他引：3  

魏俊峰  吴大清  彭金莲  刁桂仪 《矿物岩石》2002,22(2):5-8

经过酸性条件下（pH=3.1)Pb(Ⅱ）高岭石表面解吸动力学的研究，发现解吸反应与吸附反应动力学相似，也是一个二阶段的过程，即初始的快速解吸之后伴随着一个缓慢的释放过程。在快速解吸阶段，7min内解吸量即已达到41％。吸附铅没有完全解吸，有近38％残留在高岭石表面，即解吸和吸附过程不是完全可逆的。解吸过程可以用扩展Elovich方程、Elovich方程、双常数方程和一级扩散方程较好地似合。  相似文献   

MODELING THE FATE AND TRANSPORT OF HYDROPHOBIC ORGANIC COMPOUNDS IN AN UNSTEADY RIVER-ESTUARINE SYSTEM     

Su-Chin CHEN  Jan-Tai KUO 《国际泥沙研究》2002,17(3)

1 INTRODUCTION Extensive literature (Brown et al., 1985; Sawhney et al., 1981; Bierman and Swain, 1982; Connolly, 1980; Lopez-Avila and Hites, 1980; O扖onnor, 1988) described lots of sorbed pollutants or toxic substances in bed sediments of rivers, even after the effluent was halted for a long time. This is particularly true for hydrophobic organic compounds that can be sorbed on the particles and accumulated in the river bed sediments (Karickhoff et al., 1979). Pollution events of…  相似文献   

Screening model for volatile pollutants in dual porosity soils     

Mohamed M. Hantush  Rao. S. Govindaraju  Miguel A. Marioand Zhonglong Zhang 《Journal of Hydrology》2002,260(1-4):58-74

This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills.  相似文献